张修堂

1、个人简介

张修堂，男，教授，博士，博士生导师。研究方向：主要围绕在配位化学及多酸化学的基础上，聚焦多孔晶态功能材料（如MOFs, COFs及其复合材料）的设计、合成与催化功能探索；研究内容高度交叉，涉及无机化学、晶体工程学、材料化学、纳米科技、催化化学以及能源化学等多个领域。我们的主要研究内容为：(1) 催化功能导向的稳定MOFs/COFs：设计合成与功能化；(2) MOF/COF基纳米复合材料的理性构筑与催化性能研究，特别在是有机反应多相催化及光、电催化中的应用等。课题组依托氢能炭基电极材料山西省重点实验室和中北大学化学与化工学院，加上组内的科研平台建设，课题组研究内容相关的各种表征和测试条件一应俱全。组内学术气氛健康浓厚，学术思想活跃，充满正能量，为青年人才和研究生培养提供了极好的学术环境。已完成国家自然科学基金及省基金多项，发表SCI学术论文100余篇。

窗体底端

2、教育经历

2005/9~ 2008/6，山东大学, 无机化学, 博士

1999/9 ~2002/6，中国科学院福建物质结构研究所, 物理化学, 硕士

3、工作经历

2019-01 ~至今，中北大学, 化学与化工学院, 教授

2013-01 至 2018-12, 齐鲁师范学院, 化学与化工学院, 教授

2008-08 至 2012-12, 齐鲁师范学院, 化学与化工学院, 副教授

2004-10 至 2005-08, 聊城大学, 化学与化工学院, 讲师

2003-10 至 2004-09, 名古屋大学,物质科学研究中心, 助理研究员

2002-08 至 2003-09, 中国科学院福建物质结构研究所,助理研究员

4、代表性科研成果

 科研项目

1. 含Lewis碱性位点纳米微孔异金属MOFs材料的可控制备及催化CO2与环氧烷烃环加成反应研究, 自由探索类, 山西省科技厅基础研究计划, 2021-11 至 2024-10, 9万元, 在研, 主持

2. 含钼/钨氧簇金属-有机配位聚合物的设计合成及催化研究，应急管理项目，国家自然科学基金，2015/01-2015/12，10万元，已结题，主持

3. 功能多酸化合物的合成与催化、生物活性研究，青年项目，国家自然科学基金2012/01-2014/12，23万元，已结题，主持。

学术论文

[1] Xiutang Zhang,* Chong Li, and Tuoping Hu,* Multifunctional Dysprosium(III)–Organic Framework for Efficiently Catalyzing the Cycloaddition of CO₂ and Knoevenagel Condensation under Mild Conditions. ACS Sustainable Chem. Eng. 2023, 11(50), 17837–17848.

[2] Xiutang Zhang,* Xiaotong Wang, Chong Li, Tuoping Hu, Liming Fan,* Nanoporous {Co₃}-Organic framework for efficiently seperating gases and catalyzing cycloaddition of epoxides with CO₂ and Knoevenagel condensation. J. Colloid Interface Sci. 2023, 656, 127-136

[3] Bo Zhao, Chong Li, Tuoping Hu, and Xiutang Zhang,* Nanoporous {Pb₃}-Organic Framework for Catalytic Cycloaddition of CO₂ with Epoxides and Knoevenagel Condensation. ACS Appl. Nano Mater. 2023, 6(24), 23196–23206.

[4] Chong Li, Hongxiao Lv, Kun Yang*, and Xiutang Zhang,* Robust Fluorine-Functionalized {Ln₅}-Organic Frameworks for Excellent Catalytic Performance on Cycloaddition of CO₂ with Epoxides and Knoevenagel Condensation. ACS Appl. Mater. Interfaces. 2023, 15(29), 35052–35061.

[5] Chong Li, Hongtai Chen, Liming Fan*, and Xiutang Zhang,* Robust Zn(II)-Organic Framework for High Catalytic Activity on Cycloaddition of CO₂ with Epoxides and Reversible Iodine Uptake. Cryst. Growth Des. 2023, 23(7), 4953–4960.

[6] Shurong Liu, Tuoping Hu, Kun Yang*, and Xiutang Zhang,* Robust {Cd₄}-Organic Framework for Efficiently Catalyzing CO₂ Cycloaddition and Knoevenagel Condensation. Cryst. Growth Des. 2023, 23(5), 3320–3329.  

[7] Zhen-Feng Wang, Chong Li, Qi-Pin Qin*, Shuhua Zhang*, and Xiutang Zhang,* Nanoporous Lanthanide-Based MOFs for Catalyzing the Cycloaddition of CO₂ and the Knoevenagel Condensation. ACS Appl. Nano Mater. 2023, 6(24), 23430–23441.

[8] Hongxiao Lv, Liming Fan*, Chenxu Jiao*, and Xiutang Zhang,* Heterometallic YbCo–Organic Framework for Efficiently Catalyzing Cycloaddition of CO₂ with Epoxides and Knoevenagel Condensation. Cryst. Growth Des. 2023, 23(4), 2882–2892.

[9] Shurong Liu, Hongtai Chen, Liming Fan*, and Xiutang Zhang,* Highly Robust {In₂}–Organic Framework for Efficiently Catalyzing CO₂ Cycloaddition and Knoevenagel Condensation. Inorg. Chem. 2023, 62(8), 3562–3572.

[10] Hongxiao Lv, Liming Fan, Tuoping Hu, Chenxu Jiao* and Xiutang Zhang,* A highly robust cluster-based indium(III)–organic framework with efficient catalytic activity in cycloaddition of CO2 and Knoevenagel condensation. Dalton Trans., 2023, 52, 3420–3430.

[11] Zhengguo Zhang, Shurong Liu, Youbin Liu*, and Xiutang Zhang,* Robust {Cd₂Zn}n–Organic Framework for Efficiently Catalyzing CO₂ Cycloaddition and Knoevenagel Condensation. Cryst. Growth Des. 2023, 23(9), 6701–6711.

[12] Dongsheng Zhao, Wenqian Li, Rongmei Wen, Wencui Li, Xin Liu, Xiutang Zhang,* Liming Fan,* Tb(III) functionalized MOF based self-calibrating sensor integrated with logic gate operation for efficient epinephrine detection in serum. J. Rare Earths, 2023, https://doi.org/10.1016/j.jre.2023.04.007.

[13] Ruihong Guo, Yujuan Zhang, Xiutang Zhang, Mingming Ma, Tuoping Hu,* Enhanced catalytic oxidation of hydrazine of CoO/Co₃O₄ heterojunction on N-doped carbon. Electrochim Acta. 2023, 458, 142537.

[14] Ruihong Guo, Yujuan Zhang, Xiutang Zhang, Tuoping Hu,* Ni/NiO heterojunction anchored on N-doped carbon for the enhanced methanol oxidation. J. Alloys Compd. 2023, 960, 170886.

[15] Xiaoyu Chi, Lingling Gao, Yujuan Zhang, Xiutang Zhang, Tuoping Hu,* Nickel nanocrystals anchored nitrogen-doped carbon derived from eggshell membrane as an efficient catalyst for the electrocatalytic oxidation of urea. Appl. Surf. Sci. 2023, 609, 155457.

[16] Ruihong Guo, Lingling Gao, Yujuan Zhang, Xiutang Zhang, Mingming Ma, Tuoping Hu, Enhancing hydrazine-assisted hydrogen production by constructing CoP-Co2P bifunctional catalysts. Appl. Surf. Sci. 2023, 617, 156602.

[17] Na Gao, Lingling Gao, Xiutang Zhang, Yujuan Zhang, Tuoping Hu, NiO nanocrystal anchored on pitaya peel-derived carbon laminated mesoporous composites for the electrocatalytic oxidation of ethanol. J. Alloys Compd. 2023, 947, 169485.

[18] Jiangtao Ling, Ruihong Guo, Yujuan Zhang, Xiutang Zhang, Tuoping Hu. Enhanced methanol oxidation activity of porous layered Ni/CeO₂@CN nanocomposites in alkaline medium. Appl. Surf. Sci. 2023, 631, 157499.

[19] Manman Hu, Yujuan Zhang, Ruihong Guo, Xiutang Zhang, Tuoping Hu, In situ growth of NiWO₄/WO₂ nanocrystals on CC for the enhanced electrocatalytic oxidation of methanol. J. Alloys Compd. 2024, 976, 172980.

[20] Fangshuo Jia, Yujuan Zhang, Peng Zhang, Xiutang Zhang, Tuoping Hu, In situ growth of Ni/Ni₃S₂–MoO₂ nanocrystals on carbon cloth for the enhanced electrocatalytic oxidation of methanol. Appl. Surf. Sci. 2023, 640, 158348.

[21] Zhengguo Zhang, Kun Yang, Shurong Liu, Xiutang Zhang,* A highly robust {ZnTb}n-Organic framework for excellent catalytic performance on cycloaddition reaction of epoxides with CO₂. Microporous and Mesoporous Materials, Micropor. Mesopor. Mater. 2023, 356, 112592.

[22] Zhengguo Zhang, Hongxiao Lv, Kun Yang and Xiutang Zhang,* [Mo₈O₂₆]⁴⁻-based multifunctional hybrid material for high catalytic performance on the cycloaddition of CO₂, esterification and knoevenagel condensation. Dalton Trans., 2023, 52, 7119-7128.

[23] Dongsheng Zhao, Wenqian Li, Rongmei Wen, Nana Lei, Wencui Li, Xin Liu, Xiutang Zhang*, and Liming Fan,* Eu(III)-Functionalized MOF-Based Dual-Emission Ratiometric Sensor Integrated with Logic Gate Operation for Efficient Detection of Hippuric Acid in Urine and Serum. Inorg. Chem. 2023, 62(6), 2715-2725.

[24] Tao Zhang, Hongtai Chen, Linyan Wang, Yurong Liang*, and Xiutang Zhang,* Nanochannel-Based Heterometallic {Co^IITb^III}-Organic Framework for Fluorescence Recognition of Tryptophan and Catalytic Cycloaddition of Epoxides with CO₂. ACS Appl. Nano Mater. 2022, 5(10), 15220-15227.

[25] Hongxiao Lv, Hongtai Chen, Liming Fan*, and Xiutang Zhang,* Nanocage-Based Tb³⁺-Organic Framework for Efficiently Catalyzing the Cycloaddition Reaction of CO₂ with Epoxides and Knoevenagel Condensation. Inorg. Chem. 2022, 61(39), 15558–15568.

[26] Shurong Liu, Hongtai Chen, and Xiutang Zhang*, Bifunctional {Pb₁₀K₂}–Organic Framework for High Catalytic Activity in Cycloaddition of CO₂ with Epoxides and Knoevenagel Condensation. ACS Catal. 2022, 12(16), 10373–10383.

[27] Hongtai Chen, Tao Zhang, Shurong Liu, Hongxiao Lv, Liming Fan*, and Xiutang Zhang,* Fluorine-Functionalized NbO-Type {Cu₂}-Organic Framework: Enhanced Catalytic Performance on the Cycloaddition Reaction of CO₂ with Epoxides and Deacetalization-Knoevenagel Condensation. Inorg. Chem., 2022, 61(30), 11949–11958.

[28] Hongxiao Lv, Hongtai Chen, Tuoping Hu and Xiutang Zhang,* Nanocage-based {In₂Tm₂}-organic framework for efficiently catalyzing the cycloaddition reaction of CO₂ with epoxides and Knoevenagel condensation. Inorg. Chem. Front., 2022, 9, 5788–5798.

[29] Shurong Liu, Hongtai Chen, Hongxiao Lv, Qi-Pin Qin,* Liming Fan* and Xiutang Zhang,* Chemorobust 4p-5p {InPb}-organic framework for efficiently catalyzing cycloaddition of CO₂ with epoxides and deacetalization-Knoevenagel condensation. Mater. Today Chem., 2022, 24, 100984.

[30] Yanpeng Gao, Le Guo, Xiutang Zhang,* A highly robust lutecium(III)-organic framework for the high catalytic performance on the chemical fixation CO₂. J. Mol. Struct. 2023, 1272, 134192.

[31] Liming Fan, Dongsheng Zhao, Bei Li, Feng Wang, Yuxin Deng, Yuxin Peng, Xin Wang, Xiutang Zhang,* Luminescent binuclear Zinc(II) organic framework as bifunctional water-stable chemosensor for efficient detection of antibiotics and Cr(VI) anions in water. Spectrochim Acta A. 2022, 264, 120232.

[32] Hongtai Chen, Zhengguo Zhang, Hongxiao Lv, Shurong Liu and Xiutang Zhang*, Investigation on the Catalytic Behavior of A Novel Thulium-Organic Framework with A Planar Tetranuclear {Tm₄} Cluster as the Active Center for Chemical CO₂ Fixation. Dalton Trans., 2022, 51, 532–540.

[33] Tao Zhang, Zhengguo Zhang, Hongtai Chen, Xiutang Zhang* and Qiaoling Li*, Catalytic Investigation of CO₂ Chemical Fixation and the Knoevenagel Condensation Reaction for a Tm^III–Organic Framework. Cryst. Growth Des. 2022, 22, 304–312.

[34] Hongxiao Lv, Liming Fan, Hongtai Chen, Xiutang Zhang* and Yanpeng Gao*, Nanochannel-Based {BaZn}-Organic Framework for Catalytic Activity on Cycloaddition Reaction of Epoxides with CO₂ and Deacetalization-Knoevenagel Condensation. Dalton Trans., 2022, 51, 3546–3556.

[35] Hongxiao Lv, Zhengguo Zhang, Liming Fan,* Yanpeng Gao* and Xiutang Zhang*, A Nanocaged Cadmium-Organic Framework with High Catalytic Activity on the Chemical Fixation of CO₂ and Deacetalization-Knoevenagel Condensation. Micropor. Mesopor. Mater. 2022, 335, 111791.

[36] Hongtai Chen, Shurong Liu, Hongxiao Lv, Qi-Pin Qin*, and Xiutang Zhang*, Nanoporous {Y₂}-Organic Frameworks for Excellent Catalytic Performance on the Cycloaddition Reaction of Epoxides with CO₂ and Deacetalization–Knoevenagel Condensation. ACS Appl. Mater. Interfaces 2022, 14, 18589–18599.

[37] Tao Zhang, Hongtai Chen, Shurong Liu, Hongxiao Lv, Xiutang Zhang* and Qiaoling Li*, Highly Robust {Ln₄}-Organic Frameworks (Ln = Ho, Yb) for Excellent Catalytic Performance on Cycloaddition Reaction of Epoxides with CO₂ and Knoevenagel Condensation. ACS Catal. 2021, 11, 14916–14925.

[38] Hongtai Chen, Liming Fan and Xiutang Zhang*, One Robust Microporous Tm^III-organic Framework for Highly Catalytic Activity on Chemical CO₂ Fixation and Knoevenagel Condensation. Inorg. Chem. 2021, 60, 1028−1036.

[39] Hongtai Chen, Lei Feng, Xiutang Zhang,* Zhi-Yong Gao and Di Sun*, Robust Heterometallic Co^IILa^III₂–Organic Framework for the Highly Efficient Separation of Acetylene from Light Hydrocarbon Mixtures. Inorg. Chem. 2021, 60, 2878–2882.

[40] Hongtai Chen, Liming Fan, Tuoping Hu and Xiutang Zhang*, 6s-3d {Ba₃Zn₄}–Organic Framework as an Effective Heterogeneous Catalyst for Chemical Fixation of CO₂ and Knoevenagel Condensation Reaction. Inorg. Chem. 2021, 60, 3384–3392.

[41] Hongtai Chen, Liming Fan, Tuoping Hu and Xiutang Zhang,* Template-Induced {Mn₂}–Organic Framework with Lewis Acid–Base Canals as a Highly Efficient Heterogeneous Catalyst for Chemical Fixation of CO₂ and Knoevenagel Condensation. Inorg. Chem. 2021, 60, 7276–7283

[42] Hongtai Chen, Liming Fan, Tuoping Hu and Xiutang Zhang*, V=O Functionalized {Tm₂}-Organic Framework Designed by Postsynthesis Modification for Catalytic Chemical Fixation of CO₂ and Oxidation of Mustard Gas. Inorg. Chem. 2021, 60, 7, 5005–5013.

[43] Hongtai Chen, Zhengguo Zhang, Tuoping Hu and Xiutang Zhang*, An NH₂-modified {Eu^III₂}–Organic Framework for the Efficient Chemical Fixation of CO₂ and Highly Selective Sensing of 2,4,6-Trinitrophenol. Inorg. Chem. Front. 2021, 8, 4376–4385.

[44] Hongtai Chen, Zhengguo Zhang, Tuoping Hu and Xiutang Zhang*, Nanochannel {InZn}–Organic Framework with a High Catalytic Performance on CO₂ Chemical Fixation and Deacetalization–Knoevenagel Condensation. Inorg. Chem. 2021, 60, 16429–16438.

[45] Feng Wang, Fengkun Tian, Yuxin Deng, Lulu Yang, Huihui Zhang, Dongsheng Zhao, Bei Li, Xiutang Zhang* and Liming Fan*, Cluster-Based Multifunctional Copper(II) Organic Framework as a Photocatalyst in the Degradation of Organic Dye and as an Electrocatalyst for Overall Water Splitting. Cryst. Growth Des. 2021, 21, 4242–4248.

[46] Dongsheng Zhao, Junqi Song, Xiutang Zhang,* Feng Wang, Bei Li, Lulu Yang, Yuxin Deng, Qingbo Li* and Liming Fan*, A Pillar-layered Binuclear 3D Cobalt(II) Coordination Polymer as An Electrocatalyst for Overall Water Splitting and as A Chemosensor for Cr(VI) Anion Detection. CrystEngComm, 2021, 23, 6245–6252.

[47] Liming Fan,* Dongsheng Zhao, Bei Li, Xi Chen, Feng Wang, Yuxin Deng, Yulan Niu* and Xiutang Zhang*, An Exceptionally Stable Luminescent Cadmium(II) Metal–Organic Framework as A Dual-functional Chemosensor for Detecting Cr(VI) Anions and Nitro-containing Antibiotics in Aqueous Media. CrystEngComm, 2021, 23, 1218–1225

[48] Liming Fan, Dongsheng Zhao, Huihui Zhang, Feng Wang, Bei Li, Lulu Yang, Yuxin Deng, Xiutang Zhang, A hydrolytically stable amino-functionalized Zinc(II) metal-organic framework containing nanocages for selective gas adsorption and luminescent sensing. Micropor. Mesopor. Mater. 2021, 326, 111396.

[49] Hongtai Chen, Liming Fan, Xiutang Zhang*, Lin-Na Gao and Di Sun*, A Highly Robust Heterometallic Tb^III/Ni^II–Organic Framework for C₂ Hydrocarbon Separation and Capture, Chem. Commun., 2020, 56, 2047−2050. 

[50] Hongtai Chen, Liming Fan, Xiutang Zhang* and Lufang Ma*, Nanocage-Based In^III{Tb^III}₂-Organic Framework Featuring Lotus-Shaped Channels for Highly Efficient CO₂ Fixation and I₂ Capture. ACS Appl. Mater. Interfaces 2020, 12, 27803−27811.

[51] Hongtai Chen, Liming Fan and Xiutang Zhang*, Highly Robust 3s−3d {CaZn}−Organic Framework for Excellent Catalytic Performance on Chemical Fixation of CO₂ and Knoevenagel Condensation Reaction. ACS Appl. Mater. Interfaces 2020, 12, 54884−54892.

[52] Hongtai Chen, Liming Fan, and Xiutang Zhang*, Nanoporous Zn^II/Tb^III−Organic Frameworks for CO₂ Conversion, ACS Appl. Nano Mater. 2020, 3, 7201−7210.

[53] Hongtai Chen, Liming Fan, Xiutang Zhang* and Lufang Ma*, Robust Heterometallic Tb^III/Mn^II–Organic Framework for CO₂/CH₄ Separation and I₂ Adsorption, ACS Appl. Nano Mater. 2020, 3, 2680−2686.

[54] Hongtai Chen, Liming Fan, Hongxiao Lv and Xiutang Zhang*, Robust Anionic Ln^III−Organic Frameworks: Chemical Fixation of CO₂, Tunable Light Emission, and Fluorescence Recognition of Fe³⁺, Inorg. Chem. 2020, 59, 13407−13415.

[55] Hongxiao Lv, Hongtai Chen, Liming Fan and Xiutang Zhang*, Heterometallic {ZnEu}-Metal–organic Framework for Efficient Chemical Fixation of CO₂. Dalton Trans., 2020, 49, 14656–14664.

发明专利

[1] 张修堂; 李崇; 范黎明; 胡拖平; Heterogeneous metal(TbSn)-organic framework compound with chemical stability, 2024-1-24, F/PT/NC/2024/10778

[2] 张修堂; 李崇; 范黎明; 胡拖平; NH₂ functionalized InDy heterometal-organic framework compound, preparation method and application, 2024-7-5, F/PT/NC/2024/12210

5、联系方式

邮箱： xiutangzhang@163.com